Catalytic Enantioselective Diarylation of Alkenes
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https://figshare.com/articles/dataset/Catalytic_Enantioselective_Diarylation_of_Alkenes/2105029
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资源简介：
A method for the catalytic enantioselective
diarylation of alkenes
is presented. The method allowed for the synthesis of highly enantioenriched
2,3-dihydrobenzofurans and indolines containing molecules from readily
available substrates. Furthermore, this method allowed for the enantioselective
synthesis of quaternary carbons. Based on mechanism studies, the process
likely functions by enantioselective insertion of an alkene into an
Ar–CuBenzP* complex to generate a Csp3–Cu
complex. Capture of this intermediate with an ArX led to formation
of the desired product.
创建时间：
2016-02-12
