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Easy Access to Allylic Sulfones Through Transition-Metal-Free Hydrosulfonylation Of Allenes

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NIAID Data Ecosystem2026-03-13 收录
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https://figshare.com/articles/dataset/Easy_Access_to_Allylic_Sulfones_Through_Transition-Metal-Free_Hydrosulfonylation_Of_Allenes/16826218
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A Brønsted acid-mediated addition of (hetero)­aryl and (cyclo)­alkyl sodium sulfinates to N-allenyl derivatives, which proceeds in water, is described under very smooth conditions. This reaction provided a practical and efficient protocol for the regio- and stereoselective synthesis of allylic sulfones in an atom- and step-economic fashion.
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2021-10-18
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