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Rhodium(I) metallacycles based on alkylated-PTA scaffolds: Synthesis and evaluation as hydroformylation catalyst precursors

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Figshare2020-05-05 更新2026-04-28 收录
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https://figshare.com/articles/dataset/Rhodium_I_metallacycles_based_on_alkylated-PTA_scaffolds_Synthesis_and_evaluation_as_hydroformylation_catalyst_precursors/12055221
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A series of rhodium(I) metallacycles based on alkylated PTA complexes were synthesised and fully characterisedusing a range of spectroscopic and analytical techniques. These mononuclear Rh(I) complexes were evaluated inthe aqueous biphasic (water-toluene) hydroformylation of 1-octene, showing chemoselectivity to aldehydes
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2020-05-05
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