Unusual Metal-Coordinated Zwitterionic P−C−N−C−N−C Phosphido Adducts
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https://figshare.com/articles/dataset/Unusual_Metal_Coordinated_Zwitterionic_P_C_N_C_N_C_Phosphido_Adducts/2775790
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资源简介:
Rare examples of homodinuclear zwitterionic PdII and PtII complexes with bridging, two-coordinate P{cyclo-CH2N(R)CHN(R)CH2} ligands (R = 4-FC6H4CH2, C6H5CH2) have been characterized by single-crystal X-ray diffraction using synchrotron radiation. Short N−C distances and enlarged N−C−N bond angles support electron delocalization in the central N−C−N backbone.
创建时间:
2010-04-19



