Rhenium(I)-Catalyzed C‑Methylation of Ketones, Indoles, and Arylacetonitriles Using Methanol
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https://figshare.com/articles/dataset/Rhenium_I_-Catalyzed_C_Methylation_of_Ketones_Indoles_and_Arylacetonitriles_Using_Methanol/14453177
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A ReCl(CO)5/MeC(CH2PPh2)3 (L2) system was developed for the C-methylation reactions utilizing methanol and base, following the borrowing hydrogen strategy. Diverse ketones, indoles, and arylacetonitriles underwent mono- and dimethylation selectively up to 99% yield. Remarkably, tandem multiple methylations were also achieved by employing this catalytic system.
创建时间：
2021-04-20
