Diyne mediated formal synthesis of (−)-A26771B
收藏Figshare2022-03-11 更新2026-04-28 收录
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https://figshare.com/articles/dataset/Diyne_mediated_formal_synthesis_of_-A26771B/19346166
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A formal asymmetric synthesis of (−)-A26771B (1) has been achieved where optically active glycidol and Noyori asymmetric hydrogenation are applied to introduce asymmetric centers. Commercially available 1,7-octadiyne, (R)-glycidol and acetaldehyde are used as the starting materials. The outlined synthetic strategy involves fewer number of synthetic steps, applying simple chemical transformations.
创建时间:
2022-03-11



