A New Ni<sub>12</sub> Cluster Based on Polyoxometalate Ligands
收藏NIAID Data Ecosystem2026-03-06 收录
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A new Ni12 cluster based on polyoxometalate ligands [Ni12(OH)9WO4(W7O26(OH))(PW9O34)3]25− (1) has been assembled in aqueous solution containing [PW9O34]9−, WO42−, and NiCl2·6H2O. The Ni12 core in 1 shows a unique three-petal flower-shaped structure composed of three Ni4 cubane units. Magnetic investigation indicates the presence of dominantly ferromagnetic interactions within the Ni12 core.
创建时间：
2016-02-25
