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Gradient Isotactic Multiblock Polylactides from Aluminum Complexes of Chiral Salalen Ligands

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https://figshare.com/articles/dataset/Gradient_Isotactic_Multiblock_Polylactides_from_Aluminum_Complexes_of_Chiral_Salalen_Ligands/2320060
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资源简介:
Aluminum complexes of enantiomerically pure aminomethylpyrrolidine-based salalen ligands and their application in the stereoselective polymerization of lactide are described. Poly­(lactic acid) featuring the new gradient isotactic multiblock microstructure was synthesized by isoselective catalysts, which operate by a combination of enantiomorphic-site and chain-end control mechanisms.
创建时间:
2014-02-26
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