Cp*CoIII-Catalyzed Synthesis of Pyrido[2′,1′:2,3]pyrimido[1,6‑a]indol-5-iums via Tandem C–H Activation and Subsequent Annulation from 1‑(Pyridin-2-yl)‑1H‑indoles and Internal Alkynes
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https://figshare.com/articles/dataset/Cp_Co_sup_III_sup_-Catalyzed_Synthesis_of_Pyrido_2_1_2_3_pyrimido_1_6_i_a_i_indol-5-iums_via_Tandem_C_H_Activation_and_Subsequent_Annulation_from_1_Pyridin-2-yl_1_i_H_i_indoles_and_Internal_Alkynes/4129140
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资源简介：
A Cp*CoIII-catalyzed C2-selective C–H alkenylation/annulation cascade transformation of 1-(pyridin-2-yl)-1H-indoles with internal alkynes to afford pyrido[2′,1′:2,3]pyrimido[1,6-a]indol-5-iums is presented. Moreover, 6,7-dihydro-4H-pyrido[2′,1′:2,3]pyrimido[1,6-a]indole, a new functionalized N-fused indole core heterocycle, could be constructed effectively via reduction of pyrido[2′,1′:2,3]pyrimido[1,6-a]indol-5-ium by NaBH4.
创建时间：
2016-11-14
