Ru(II)-Catalyzed C–H Functionalization on Maleimides with Electrophiles: A Demonstration of Umpolung Strategy
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https://figshare.com/articles/dataset/Ru_II_-Catalyzed_C_H_Functionalization_on_Maleimides_with_Electrophiles_A_Demonstration_of_Umpolung_Strategy/4801885
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资源简介:
The unconventional
nucleophilic reactivity of maleimides, innate
electrophiles, has been realized under Ru(II)-catalysis such that
exposure to electrophiles delivered products of C–H chalcogenation
and amidation in good yields (up to 94%). This protocol features mild
conditions and operational simplicity with broad substrate scope,
uses an inexpensive and air-stable catalyst, and also represents the
first example of Ru(II) catalyzed C–H selenylation of alkenes.
创建时间:
2017-03-30



