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A Pentagonal Pyramidal Zirconium Imido Complex for Catalytic Hydroamination of Unactivated Alkenes

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https://figshare.com/articles/dataset/A_Pentagonal_Pyramidal_Zirconium_Imido_Complex_for_Catalytic_Hydroamination_of_Unactivated_Alkenes/3065503
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The first, isolable group 4 imido complexes capable of promoting intramolecular olefin hydroamination for the preparation of N-containing heterocycles are presented. The structurally characterized 6-coordinate bis(amidate)-supported zirconium imido complex is a rare example of distorted-pentagonal-pyramidal geometry.
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2016-02-29
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