Total Synthesis of (±)-Welwitindolinone A Isonitrile
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https://figshare.com/articles/dataset/Total_Synthesis_of_Welwitindolinone_A_Isonitrile/3239149
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资源简介:
A highly stereoselective total synthesis of the alkaloid natural product welwitindolinone A isonitrile has been completed. The synthesis utilizes a chloronium ion mediated semi-pinacol rearrangement to simultaneously install the C10 quaternary center and neopentyl chlorine and a novel anionic cyclization to construct the spiro-oxindole with complete stereocontrol.
创建时间:
2016-05-05



