Synthesis, Optical, and Redox Properties of Regioisomeric Benzoheterocycles-Fused Pyrene

A new synthetic route toward the synthesis of benzo­[b]­phospholes- and benzo­[b]­siloles-fused pyrenes using a transition metal-catalyzed C–H bond activation is described. The compounds were fully characterized including X-ray diffraction. A combined experimental and theoretical study shows that both the heteroatom and the substitution pattern impact the optical and redox properties.