A Five-Membered Ru5 Ring in a Hexagonal La14 Cage: The La14Cl20Ru5 Structure
收藏Figshare2016-02-21 更新2026-04-29 收录
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https://figshare.com/articles/dataset/A_Five_Membered_Ru_sub_5_sub_Ring_in_a_Hexagonal_La_sub_14_sub_Cage_The_La_sub_14_sub_Cl_sub_20_sub_Ru_sub_5_sub_Structure/2538121
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资源简介：
The title compound features a five-membered Ru5 ring embedded in a La14 hexagonal wheel-like cage, an incommensurate combination of the two building units. A formal electron partition of (La3+)14(Cl–)20(Ru5)22– results in a (Ru5)22– ring isoelectronic to (Cd5)2–. However, computational studies show that there is significant electron back-donation from the Ru5 ring to the La14 wheel. This interaction strongly stabilizes the Ru5 ring. The resistivity and magnetic susceptibility of the compound have also been investigated.
创建时间：
2016-02-21
