Oligomerization of Phenylacetylene to Coordinated 2,3,6-Triphenylfulvene in Molybdenum Tetracyclone Complexes
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The reaction of [Mo(CO)2(η-C4Ph4CO)2] with phenylacetylene gave [Mo(CO)(η-C4Ph4CO)(η6-2,3,6-C4H2Ph2CCHPh)], in which [2 + 2 + 1] cyclotrimerization of three alkyne molecules to give a fulvene ligand has occurred.
创建时间:
2016-02-20



