Linear α‑Olefins Obtained with Palladium(II) Complexes Bearing a Partially Oxidized Tetraphosphane
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https://figshare.com/articles/dataset/Linear_Olefins_Obtained_with_Palladium_II_Complexes_Bearing_a_Partially_Oxidized_Tetraphosphane/2266912
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资源简介：
The
coordination of Pd(II) to the 1,3-trans- and
2,3-trans-dioxides and the trioxide of cis,trans,cis-1,2,3,4-tetrakis(diphenylphosphino)cyclobutane
gave two dinuclear Pd(II) complexes, which are structural isomers,
and a mononuclear complex, respectively. The latter complexes proved
to be suitable precatalysts for the oligomerization of ethylene to
linear α-olefins (98% selectivity). The different catalytic
activity of the structural isomers was shown to depend on the dynamic
behavior
of the molecular structure.
创建时间：
2014-08-11
