Copper(I) and Copper(II) Uranyl Heterometallic Hybrid Materials
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https://figshare.com/articles/dataset/Copper_I_and_Copper_II_Uranyl_Heterometallic_Hybrid_Materials/2268676
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资源简介：
Two
copper–uranium heterometallic compounds, [(UO2)3CuIIO2(C6NO2)5] (1) and [(UO2)CuI(C6NO2)3] (2), have been synthesized
by the reaction of uranyl acetate with copper salts in the presence
of isonicotinic acid. Both compounds have been characterized by single-crystal
X-ray diffraction, IR, Raman, and UV–vis spectroscopy. In compound 1, interactions between copper and uranium centers occur and
result in a three-dimensional pillar layered structure. Compound 1 is also the first example of a heterometallic uranyl organic
framework with a trinuclear U3O18 building block.
Compound 2 is the first uranyl organic framework that
contains monovalent copper, which arises from the reaction of Cu(II)
chloride and is assumed to be due to the oxidation of chloride at
low pH.
创建时间：
2016-02-17
