Regioselective Copper-Catalyzed Boracarboxylation of Vinyl Arenes
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https://figshare.com/articles/dataset/Regioselective_Copper-Catalyzed_Boracarboxylation_of_Vinyl_Arenes/4282472
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资源简介：
Regioselective copper-catalyzed boracarboxylation
of vinyl arenes
with bis(pinacolato)diboron and carbon dioxide has been
achieved. New boron-functionalized α-aryl carboxylic acids,
including nonsteroidal anti-inflammatory drugs (NSAIDs), are obtained
in moderate to excellent yields. The synthetic utility of the transformation
was shown through subsequent derivatization of the carbon–boron
bond yielding formal hydroxy- and fluorocarboxylation products as
well as anionic difluoroboralactones.
创建时间：
2016-12-02
