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Stable Mononuclear Organometallic Pd(III) Complexes and Their C−C Bond Formation Reactivity

NIAID Data Ecosystem2026-03-06 收录

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https://figshare.com/articles/dataset/Stable_Mononuclear_Organometallic_Pd_III_Complexes_and_Their_C_C_Bond_Formation_Reactivity/2765347 数据链接链接失效反馈

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Stable Mononuclear Organometallic Pd(III) Complexes and Their C−C Bond Formation Reactivity

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创建时间：

2010-06-02

有机金属化学

催化氧化

The ligands RN(CH2-2-C5H4N)2 (L1, R = CH2CH2OH; L2, R = CH2CH2CH2OH; L3, R = 2-C6H4OH) have been designed to give dimethylplatinum(II) complexes that can activate dioxygen in the absence of a protic

NIAID Data Ecosystem100

Tungsten(0) and Rhenium(I) η 2 -Pyrrole Complexes: Dearomatization of Pyrroles and Their Facile Isomerizations, Protonations, and Reductions

有机金属化学

吡咯配位化学

Complexes of the form TpRe(CO)(MeIm)(η2-L) and TpW(NO)(PMe3)(η2-L) have been synthesized, where L = 1-methylpyrrole, 2-methylpyrrole, and 2,5-dimethylpyrrole. Depending on the nature of both the pyrro

NIAID Data Ecosystem70

Formation and Cleavage of C−C, C−O, and O−H Bonds Involving Methoxycarbyne and Hydroxycarbyne Ligands at Unsaturated Dimolybdenum Complexes

有机金属化学

反应机理

Reversible carbyne−carbyne coupling occurs upon addition of simple ligands L (CO, tBuNC) to the bis(methoxycarbyne) complex [Mo2Cp2(μ-COMe)2-(μ-PCy2)]BF4 to give the dimethoxyacetylene-bridged derivat

NIAID Data Ecosystem40

Addition of Carbon–Fluorine Bonds to a Mg(I)–Mg(I) Bond: An Equivalent of Grignard Formation in Solution

有机金属化学

格氏反应模拟

Addition of the carbon–fluorine bond of a series of perfluorinated and polyfluorinated arenes across the Mg–Mg bond of a simple coordination complex proceeds rapidly in solution. The reaction results

NIAID Data Ecosystem70

π-Conjugated Conjoined Double Helicene via a Sequence of Three Oxidative CC- and NN-Homocouplings

手性双螺旋烯合成

催化氧化偶联

Dimerization of planarized diamine 2 using benzoyl peroxide gave dihydrazine 1 in about 70% yield; that is, three dehydrogenations (one CC- and two NN-homocouplings) and two ring closures were attaine

NIAID Data Ecosystem70

Stable Mononuclear Organometallic Pd(III) Complexes and Their C−C Bond Formation Reactivity

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