Dataset : Boosting 1H and 13C NMR signals by orders of magnitude on a bench

Spectroscopic Data DNP 1T 77K 1H DNP Juice with TEMPOL at 50mM Sample : 6/2/2 DMSO-d6/H2O/D2O 200µL Topspin Folder : 20231102_HDNPjuice_50mM_CB Note : no phc1 in the data processing not to affect the integral as we have a broad signal TE : 100 / 200 / 300 substraction of the 100 TE and 1000 BG with Topspin —> exp 1 For 200 w BG1000 —> exp 2 proc 999 For 300 w BG1000 —> exp 3 proc 999 DNP : 105 / 205 / 305 MW 28,16 GHz ± 20 MHz @ 60 kHz E 105 (comp to 2) : 110 E 205 (comp to 3) : 97 E 305 (comp to 4) : 95 T build up with satrec : 206 28,18 GHz no fmod General model: val(t) = a*(1-exp(-(t)/T)+d) Coefficients (with 95% confidence bounds): T = 0.5164 (0.4523, 0.5805) a = 0.7312 (0.6996, 0.7628) d = 0.3518 (0.3163, 0.3873) T1 : 207 satrec experiment at TE General model: val(t) = a*(1-exp(-(t)/T)+d) Coefficients (with 95% confidence bounds): T = 0.5067 (0.4584, 0.555) a = 0.7826 (0.7567, 0.8085) d = 0.2713 (0.2458, 0.2967)