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Reactivity of a Pd(I)−Pd(I) Dimer with O2: Monohapto Pd Superoxide and Dipalladium Peroxide in Equilibrium

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Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Reactivity_of_a_Pd_I_Pd_I_Dimer_with_O_sub_2_sub_Monohapto_Pd_Superoxide_and_Dipalladium_Peroxide_in_Equilibrium/2679118
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The Pd(I)−Pd(I) dimer [(FPNP)Pd−]2 reacts with O2 upon exposure to light to produce either the superoxide (FPNP)PdO2 or the peroxide [(FPNP)PdO−]2, which exist in equilibrium with free O2. Both complexes contain square-planar Pd(II) centers. The unpaired electron density in (FPNP)PdO2 is localized on the superoxide ligand.
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2016-02-23
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