Synthetic Studies on the MARDi Cascade: Stereoselective Synthesis of Heterocyclic Seven-Membered Rings
收藏NIAID Data Ecosystem2026-03-06 收录
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资源简介：
A versatile stereoselective synthesis of substituted and functionalized heterocyclic seven-membered rings is described. The approach involves a formal two-carbon ring expansion of heterocyclic cyclopentanones through a base-induced anionic domino three-component transformation named the MARDi cascade leading either to oxa-, aza-, or thiacycloheptanes bearing up to five contiguous stereogenic centers.
创建时间：
2016-02-29
