A Cu(I)-Catalyzed C−H α-Amination of Esters. Direct Synthesis of Hydantoins

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A Cu(I)-Catalyzed C−H α-Amination of Esters. Direct Synthesis of Hydantoins

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2016-02-27

Experimental and Computational Study of the ( Z )‑Selective Formation of Trisubstituted Olefins and Benzo-Fused Oxacycles from the Ruthenium-Catalyzed Dehydrative C–H Coupling of Phenols with Ketones

催化有机合成

C-C偶联反应

The cationic Ru–H complex was found to be an effective catalyst for the dehydrative C–H coupling of phenols with ketones to form the trisubstituted olefin products. The coupling of phenol with linear

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Highly Enantioselective Organocatalytic Trifluoromethyl Carbinol SynthesisA Caveat on Reaction Times and Product Isolation

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反应选择性

Aldol reactions with trifluoroacetophenones as acceptors yield chiral α-aryl, α-trifluoromethyl tertiary alcohols, valuable intermediates in organic synthesis. Of the various organocatalysts examined,

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Intramolecular Pd-Mediated Processes of Amino-Tethered Aryl Halides and Ketones: Insight into the Ketone α-Arylation and Carbonyl-Addition Dichotomy. A New Class of Four-Membered Azapalladacycles

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反应机理

An exploration of the scope and limitations of Pd(0)-catalyzed intramolecular coupling reactions of amino-tethered aryl halides and ketones has been conducted. Two different and competitive reaction p

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An Electron-Rich Proazaphosphatrane for Isocyanate Trimerization to Isocyanurates

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异氰酸酯三聚反应

A facile synthesis of the new electron-rich, sterically hindered proazaphosphatrane shown above is described herein. This proazaphosphatrane catalyzes the cyclotrimerization of a wide variety of isocy

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Fast CO 2 Sequestration, Activation, and Catalytic Transformation Using N ‑Heterocyclic Olefins

CO2固定

催化有机合成

N-Heterocyclic Olefin (NHO) with high electronegativity at the terminal carbon atom was found to show a strong tendency for CO2 sequestration, affording a CO2 adduct (NHO–CO2). X-ray single crystal an

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A Cu(I)-Catalyzed C−H α-Amination of Esters. Direct Synthesis of Hydantoins

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