A Monomeric Perfluoroalkyl Iridium(III) Amido Complex with an IrN Double Bond and Its Reactions To Activate sp<sup>3</sup> Carbon−Hydrogen Bonds at Room Temperature
收藏NIAID Data Ecosystem2026-03-06 收录
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A simple iridium amido complex has been prepared and shown to contain an unambiguous IrN double bond, using X-ray crystallography and DFT calculations. The compound exhibits remarkable reactivity by activating the allylic C−H bonds of terminal alkenes at room temperature, liberating tBuNH2 and forming η3-allylic complexes of iridium.
创建时间：
2009-08-24
