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Asymmetric Synthesis of Tertiary Benzylic Alcohols

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NIAID Data Ecosystem2026-03-06 收录
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Vinyl, aryl, and alkynyl organometallics add to ketones containing a stereogenic sulfoxide. Tertiary alcohols are generated in diastereomerically and enantiomerically pure form. Reductive lithiation converts the sulfoxide into a variety of useful functional groups.

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2011-01-21
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