Gold- and Brønsted Acid-Catalyzed Cycloisomerization of 1,8-Diynyl Vinyl Acetates to Bicyclo[2.2.1]hept-2-en-7-ones

Figshare2016-11-14 更新2026-04-29 收录

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https://figshare.com/articles/dataset/Gold-_and_Br_nsted_Acid-Catalyzed_Cycloisomerization_of_1_8-Diynyl_Vinyl_Acetates_to_Bicyclo_2_2_1_hept-2-en-7-ones/4123203

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资源简介：

A synthetic method for the efficient assembly of bicyclo[2.2.1]hept-2-en-7-ones that relies on gold(I)-catalyzed Rautenstrauch rearrangement followed by Brønsted acid-mediated formal [3 + 2]-cycloaddition/deacetylation of 1,8-diynyl vinyl acetates at room temperature under atmospheric conditions is described.

创建时间：

2016-11-14