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Tetrahydrodibenzophenanthridine-Based Boron-Bridged Polycyclic Aromatic Hydrocarbons: Synthesis, Structural Diversity, and Optical Properties

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https://figshare.com/articles/dataset/Tetrahydrodibenzophenanthridine-Based_Boron-Bridged_Polycyclic_Aromatic_Hydrocarbons_Synthesis_Structural_Diversity_and_Optical_Properties/7725797
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资源简介:
A series of B←N coordinated tetrahydrodibenzo­[a,i]­phenanthridine-based polycyclic aromatic hydrocarbons (PAHs) have been designed and synthesized. All of these compounds have been characterized by multinuclear NMR spectroscopy and high-resolution mass spectrometry. Compounds 1, 2, 4, and 7 have also been characterized by single-crystal X-ray diffraction analysis. Our newly synthesized compounds exhibit good luminescence quantum yields in solution and moderate quantum yields in the solid state. Furthermore, the compounds show a large Stokes shift in comparison to the well-known boron–dipyrromethene dyes.
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2019-02-15
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