Aryl-Acetylene Layered Hybrid Perovskites in Photovoltaics

Structural, optoelectronic, photovoltaic, and supplementary characterization data for “Aryl-Acetylene Layered Hybrid Perovskites in Photovoltaics" DOI: 10.1002/anie.202417432all NMR data.zip: solid state NMR data (Figure 2b, and S9) and liquid state NMR data (Figures S2, S3, S4 and S5)Figure 2a XRD.xlsx: Data described in Figure 2a (XRD patterns) as Excel (.xl) software file.Figure 3a. uv-vis and PL of (BMAA)2PbI4, and (BDAA)PbI4.opju: data described in Figure 3a (uv-vis absorption spectra and stead state PL) as Origin (.opju) software file.Figure 3b,c,d and Figure S10. Transient Absorption Spectroscopy data.opju: Transient Absorption Spectroscopy data of (BMAA)2PbI4, (BDAA)PbI4, and (PDMA)PbI4 films) in addition to the corresponding photobleaching kinetics (Figure S10) as Origin (.opju) software file.Figure 3e. irradiation data of BDAAI2.opju: data described in Figure 3e (uv-vis absorption spectra OF BDAAI2 with response to irradiation) as Origin (.opju) software file.Figure 3f. irradiation data of (BDAA)PbI4.opju: data described in Figure 3F (uv-vis absorption spectra OF (BDAA)PbI4 with response to irradiation) as Origin (.opju) software file.Figure 4a. Photovoltaic characteristics of the devices.opju: data described in Figure 4a (photovoltaics parameters for the FAPbI3-based devices) as Origin (.opju) software fileFigure 4b. PLQY without spiro.opju: : data described in Figure 4b (PLQY) for perovskite films without spiro-OMeTAD addition as Origin (.opju) software file.Figure 4c. PLQY with spiro.opju: data described in Figure 4c (PLQY) for perovskite films upon spiro-OMeTAD addition as Origin (.opju) software file.Figure 5b. Stability data.opju: data described in Figure 5b (operational stability of the perovskite devices)as Origin (.opju) software file.

Supporting Information Data.zip: Data described in the Supporting Information:Figure S8 (ATR FTIR spectra) as Origin (.opju) software file;Figure S11 and S12 (UV-Vis spectra for (BMAA)I and (BDAA)PbI4) as Excel (.csv) software file;Figure S14 (UV-Vis spectra for (BMAA)2PbI4), Figure S15-S16 (galvanostatic polarization and impedance measurements for (BDAA)PbI4 ; Figure S18 (XRD patterns for the devices); Figure S22 (Pb and N XPS spectra); Figure S24 (UV-Vis and Tauc plot for the films); Figure S25 (JV scans for FAPbI3 and triple cation devices); Figure S26 (photovoltaic characteristics of the triple cation devices); Figure S27 (IPCE & integrated current density for FaPbI3 and triple cation devices); and Figure S28 (TRPL measurements of the perovskite films) as Origin (.opju) software files.