The Reaction of [Cp*RhCl<sub>2</sub>]<sub>2</sub>, Aniline, and a Terminal Alkyne: Formation of Cyclometalated Rhodium(III) Complexes
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The reaction of [Cp*RhCl2]2 with an aniline (R′NH2) and a terminal alkyne (RCCH) afforded the N-containing cyclometalated rhodium complexes Cp*Rh(Cl)[N(R′)C(CH2R)CHCR] via a hydroamination and a 1,2-insertion of an alkyne. A reaction pathway has been proposed on the basis of deuterium labeling experiments and computational studies.
创建时间：
2016-02-20
