Record Antiferromagnetic Coupling for a 3d/4d Cyanide-Bridged Compound
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https://figshare.com/articles/dataset/Record_Antiferromagnetic_Coupling_for_a_3d_4d_Cyanide_Bridged_Compound/2273926
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The pentanuclear compound [VII(tmphen)2]3[MoIII(CN)6]2 (tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline) exhibits a record antiferromagnetic exchange coupling constant of JV–Mo = −114 cm–1. This is the first example of a heterobimetallic cyanide compound with such strong magnetic coupling.
创建时间：
2016-02-17
