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Record Antiferromagnetic Coupling for a 3d/4d Cyanide-Bridged Compound

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Figshare2016-02-17 更新2026-04-29 收录
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The pentanuclear compound [VII(tmphen)2]3[MoIII(CN)6]2 (tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline) exhibits a record antiferromagnetic exchange coupling constant of JV–Mo = −114 cm–1. This is the first example of a heterobimetallic cyanide compound with such strong magnetic coupling.

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2016-02-17
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