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Verdazyl Radical, a Building Block for a Six-Spin-Center 2p–3d–4f Single-Molecule Magnet

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NIAID Data Ecosystem2026-03-09 收录
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https://figshare.com/articles/dataset/Verdazyl_Radical_a_Building_Block_for_a_Six-Spin-Center_2p_3d_4f_Single-Molecule_Magnet/4234967
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The versatile verdazyl family provides a new member as its reduced form 1,5-dimethyl-3-[3′-(hydroxymethyl)-2′-pyridine]-6-oxotetrazane (H3vdpyCH2OH). Upon oxidation and deprotonation in the presence of the acetate salts of CoII and DyIII, the vdpyCH2OH radical is able to self-assemble [(vdpyCH2O)2Co2Dy2ac8] (Hac = HO2CCH3), a 2p–3d–4f cluster displaying single-molecule-magnet properties.
创建时间:
2016-11-16
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