Synthesis and Characterization of a Water Stable Uranyl(V) Complex
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https://figshare.com/articles/dataset/Synthesis_and_Characterization_of_a_Water_Stable_Uranyl_V_Complex/7201118
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We have identified a polydentate aminocarboxylate ligand that stabilizes uranyl(V) in water. The mononuclear [UO2(dpaea)]X, (dpaeaH2 = Bis(pyridyl-6-methyl-2-carboxylate)-ethylamine; X = CoCp2*+ or X = K(2.2.2.cryptand) complexes have been isolated from anaerobic organic solution, crystallographically and spectroscopically characterized both in water and organic solution. These complexes disproportionate at pH ≤ 6, but are stable in anaerobic water at pH 7–10 for several days.
创建时间：
2018-10-12
