Selective Boryl Silyl Ether Formation in the Photoreaction of Bisboryloxide/Boroxine with Hydrosilane Catalyzed by a Transition-Metal Carbonyl Complex
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https://figshare.com/articles/dataset/Selective_Boryl_Silyl_Ether_Formation_in_the_Photoreaction_of_Bisboryloxide_Boroxine_with_Hydrosilane_Catalyzed_by_a_Transition_Metal_Carbonyl_Complex/2302165
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资源简介：
Selective B–O–Si
bond formation was achieved in the
reaction of bisboryloxide O(Bpin)2 (pin = (OCMe2)2)/boroxine (MeBO)3 system with tertiary silane
R3SiH in the presence of stoichiometric water and a catalytic
amount of [M](CO)5 ([M] = Mo(CO), W(CO), Fe) to give boryl
silyl ethers. Moreover, this reaction can be applied to various hydrosilanes
(disilyl compounds and secondary silanes) and hydrogermane. Some of
the boryl silyl ethers thus formed were confirmed by X-ray analysis.
创建时间：
2014-04-30
