A Neutral, Monomeric Germanium(I) Radical
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https://figshare.com/articles/dataset/A_Neutral_Monomeric_Germanium_I_Radical/2633437
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资源简介：
Stoichiometric reduction of the bulky β-diketiminato germanium(II) chloride complex [(ButNacnac)GeCl] (ButNacnac = [{N(Dip)C(But)}2CH]−, Dip = C6H3Pri2-2,6) with either sodium naphthalenide or the magnesium(I) dimer [{(MesNacnac)Mg}2] (MesNacnac = [(MesNCMe)2CH]−, Mes = mesityl) afforded the radical complex [(ButNacnac)Ge:]• in moderate yields. X-ray crystallographic, EPR/ENDOR spectroscopic, computational, and reactivity studies revealed this to be the first authenticated monomeric, neutral germanium(I) radical.
创建时间：
2011-07-06
