Stereoselective Synthesis of the Diazonamide A Macrocyclic Core
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https://figshare.com/articles/dataset/Stereoselective_Synthesis_of_the_Diazonamide_A_Macrocyclic_Core/2184160
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Stereoselective synthesis of the right-hand heteroaromatic macrocycle of diazonamide A features C16–C18 bond formation in the Suzuki–Miyaura cross-coupling and atropodiastereoselective Dieckmann-type macrocyclization as key steps. The Suzuki–Miyaura cross-coupling gave the best yields when it was catalyzed by a palladium–dioxygen complex.
创建时间：
2016-02-14
