Cyclometalation via Carbon–Fluorine Bond Activation Induced by Silver Particles
收藏Figshare2017-02-27 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Cyclometalation_via_Carbon_Fluorine_Bond_Activation_Induced_by_Silver_Particles/4698049
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On treatment with either freshly prepared silver nanoparticles or silver particles mechanochemically generated by stirring silver(I) oxide in dichloromethane, the complex [Cp*IrCl2(κC-MeNC3H2NCH2C6F5)] underwent a rapid and clean cyclometalation involving carbonfluorine bond fission to afford the product [Cp*IrCl(κC2-MeNC3H2NCH2C6F4)].
创建时间:
2017-02-27



