Efficient Synthesis of N-Alkylated α,β-Unsaturated Ketonitrones via Cu-Catalyzed Rearrangement
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https://figshare.com/articles/dataset/Efficient_Synthesis_of_i_N_i_Alkylated_Unsaturated_Ketonitrones_via_Cu_Catalyzed_Rearrangement/2264269
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资源简介:
N-Alkylated unsaturated ketonitrones were efficiently synthesized from propargyloxyamines using Cu catalysts. Mechanistic studies suggest that the rearrangement reaction proceeds via Cu-catalyzed intramolecular hydroamination, followed by thermally induced electrocyclic ring opening.
创建时间:
2016-02-17



