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Efficient Synthesis of N-Alkylated α,β-Unsaturated Ketonitrones via Cu-Catalyzed Rearrangement

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Figshare2016-02-17 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Efficient_Synthesis_of_i_N_i_Alkylated_Unsaturated_Ketonitrones_via_Cu_Catalyzed_Rearrangement/2264269
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资源简介:
N-Alkylated unsaturated ketonitrones were efficiently synthesized from propargyl­oxyamines using Cu catalysts. Mechanistic studies suggest that the rearrangement reaction proceeds via Cu-catalyzed intramolecular hydroamination, followed by thermally induced electrocyclic ring opening.
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2016-02-17
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