1,2-Hydrogen Migration to a Saturated Ruthenium Complex via Reversal of Electronic Properties for Tin in a Stannylene-to-Metallostannylene Conversion
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https://figshare.com/articles/dataset/1_2_Hydrogen_Migration_to_a_Saturated_Ruthenium_Complex_via_Reversal_of_Electronic_Properties_for_Tin_in_a_Stannylene_to_Metallostannylene_Conversion/2247559
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资源简介：
An
intramolecular 1,2(α)-H migration in a saturated ruthenium
stannylene complex, to form a ruthenostannylene complex, involves
a reversal of the role for a coordinated stannylene ligand, from that
of an electron donor to an acceptor in the transition state. This
change in the bonding properties for a stannylene group, with a simple
molecular motion, lifts the usual requirement for generation of an
unsaturated metal center in migration chemistry.
创建时间：
2016-02-16
