Palladium(II) Terminal Phosphido Complexes Derived from Cyclometalated Dimesitylphosphine: Synthesis, Structure, and Low-Barrier Phosphorus Inversion
收藏NIAID Data Ecosystem2026-03-06 收录
下载链接：
https://figshare.com/articles/dataset/Palladium_II_Terminal_Phosphido_Complexes_Derived_from_Cyclometalated_Dimesitylphosphine_Synthesis_Structure_and_Low-Barrier_Phosphorus_Inversion/3772518
下载链接
链接失效反馈官方服务：
资源简介：
The cyclometalated cationic Pd(II) and Pt(II) complexes [M(diphos)(CH2C6H2Me2P(Mes)(H))][X] (5−8: M = Pd, Pt; diphos = dppe (Ph2PCH2CH2PPh2), dppen (cis-Ph2PCHCHPPh2);
Mes = 2,4,6-Me3C6H2; X = OTf, BF4) were prepared by thermolysis of the cations [M(diphos)(Me)(PMes2H)][X]. Deprotonation of 5−8 gave the neutral phosphido complexes M(diphos)(CH2C6H2Me2P(Mes)) (9−12); the Pd(II) compounds 9 and 11 are the first examples of stable
palladium terminal phosphido alkyl complexes, and their crystal structures were determined.
Fluxional processes in complexes 9−12 were studied by variable-temperature NMR
spectroscopy; the spectra are consistent with low barriers to phosphorus inversion.
创建时间：
2016-08-26
