Tandem Dienone Photorearrangement–Cycloaddition for the Rapid Generation of Molecular Complexity
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https://figshare.com/articles/dataset/Tandem_Dienone_Photorearrangement_Cycloaddition_for_the_Rapid_Generation_of_Molecular_Complexity/2349196
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资源简介:
A tandem
dienone photorearrangement–cycloaddition (DPC) reaction
of novel cyclohexadienone substrates tethered with various 2π
and 4π reaction partners resulted in the formation of polycyclic,
bridged frameworks. In particular, use of alkynyl ether-tethered substrates
led to (3 + 2) cycloaddition to afford strained alkenes which could
be further elaborated by intra- and intermolecular cycloaddition chemistry
to produce complex, polycyclic chemotypes.
创建时间:
2016-02-18



