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Targeted Synthesis of Heterobimetallic Compounds Containing a Discrete Vanadium(V)−μ-Oxygen–Iron(III) Core

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https://figshare.com/articles/dataset/Targeted_Synthesis_of_Heterobimetallic_Compounds_Containing_a_Discrete_Vanadium_V_Oxygen_Iron_III_Core/2505325
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Heterobimetallic compounds [L1OVVO→Fe­(metsalophen)­(H2O)] (1) and [L2OVVO→Fe­(metsalophen)­(H2O)]­CH3CN (2), where H2L1 and H2L2 are tridentate dithiocarbazate-based Schiff base ligands, containing a discrete VV–μ-O–FeIII angular core have been synthesized for the first time through a targeted synthesis route: confirmation in favor of such a heterobimetallic core structure has come from single-crystal X-ray diffraction analysis and electrospray ionization mass spectrometry.
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2012-07-16
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