Homoannular Double Friedel–Crafts Acylation of Phosphametallocenes
收藏NIAID Data Ecosystem2026-03-07 收录
下载链接：
https://figshare.com/articles/dataset/Homoannular_Double_Friedel_Crafts_Acylation_of_Phosphametallocenes/2611597
下载链接
链接失效反馈官方服务：
资源简介：
Two reaction modes of homoannular double Friedel–Crafts acylation are realized using polyalkylphosphametallocenes as substrates. The first example is the reaction of tetra(tert-butyl)diphospharuthenocene with excess acetyl chloride/aluminum chloride, giving a 2,3-double Friedel–Crafts acylation product with an elimination of one of the tert-butyl groups. The other is the 2,5-diacylation of 1′,2′,3,3′,4,4′,5′-Me7-phosphaferrocene using an acyl chloride/aluminum chloride mixture. These reactions provide rare examples of doubly functionalized phosphametallocenes.
创建时间：
2016-02-22
