A Highly Efficient Palladacycle Catalyst for Hydrophenylation of C-, N-, and O-Substituted Bicyclic Alkenes under Aerobic Condition
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https://figshare.com/articles/dataset/A_Highly_Efficient_Palladacycle_Catalyst_for_Hydrophenylation_of_C_N_and_O_Substituted_Bicyclic_Alkenes_under_Aerobic_Condition/3276118
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资源简介：
A new phosphine-free palladacycle catalyst 4 was prepared
from benzyl oxazoline in high yield and fully characterized.
With it as catalyst, hydrophenylation reactions of a wide
range of bicyclic alkenes, not only norbornene and norbornadiene but also oxa- and aza-bicyclic alkenes, with iodobenzene proceeded smoothly under aerobic condition without
exclusion of water. Up to 1.7 × 106 TON as well as 1.2 ×
105 TOF were achieved.
创建时间：
2016-05-05
