An Alkynylaminomethylaluminum Species with a Six-Membered Chair Conformation Al2C2N2 Framework: A New Path to Geminal N/Al Frustrated Lewis Pairs
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https://figshare.com/articles/dataset/An_Alkynylaminomethylaluminum_Species_with_a_Six_Membered_Chair_Conformation_Al_sub_2_sub_C_sub_2_sub_N_sub_2_sub_Framework_A_New_Path_to_Geminal_N_Al_Frustrated_Lewis_Pairs/2519059
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The hydroalumination of the fused pentahydride aminocarbaaluminum species [(C6H3(iPr2-2,6)N(μ-AlH2)CH2)2(μ-AlH)NMe3] (1) with phenylacetylene resulted in the unexpected dimer [C6H3(iPr2-2,6)(*N)HCH2Al(CCPh)2]2 (2) with chiral centers at the nitrogen atoms. Compound 2 was characterized by X-ray structural analysis and contains geminal frustrated Lewis pairs.
创建时间：
2016-02-20
