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Peri-Diaurated Naphthalene: Synthesis and Reactions of a New Class of Organogold(I) Complexes Containing Bridging, Dianionic Naphthalenediyl Ligands

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Peri_Diaurated_Naphthalene_Synthesis_and_Reactions_of_a_New_Class_of_Organogold_I_Complexes_Containing_Bridging_Dianionic_Naphthalenediyl_Ligands/2854996
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The dinuclear gold(I) compound [Au2(μ-C10H6){μ-Ph2P(CH2)2PPh2}] was prepared in high yield by the reaction of 1,8-bis(trimethylstannyl)naphthalene with [Au2Cl2(μ-Ph2P(CH2)2PPh2)]. Oxidative addition with halogens results in the formation of the dihalodigold(II) complexes [Au2(X)2(μ-C10H6){μ-Ph2P(CH2)2PPh2}] (X = Cl, Br, I) containing a gold−gold bond.
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2016-02-26
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