Bioinspired Total Synthesis of (±)-Yezo’otogirin C
收藏Figshare2016-02-18 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Bioinspired_Total_Synthesis_of_Yezo_otogirin_C/2331568
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资源简介：
The first and protective group-free total synthesis of (±)-yezo’otogirin C has been achieved from 3-methyl-4-prenylcyclohex-2-enone in eight steps with 23% overall yield. The tricyclic core of (±)-yezo’otogirin C was established via a bioinspired oxidative cascade cyclization strategy using Mn(II)/Mn(III) and O2, followed by reduction of the peroxy-bridged intermediate using thiourea in refluxing methanol.
创建时间：
2016-02-18
