Chiral, Sterically Demanding N‑Heterocyclic Carbenes Fused into a Heterobiaryl Skeleton: Design, Synthesis, and Structural Analysis
收藏NIAID Data Ecosystem2026-03-08 收录
下载链接：
https://figshare.com/articles/dataset/Chiral_Sterically_Demanding_N_Heterocyclic_Carbenes_Fused_into_a_Heterobiaryl_Skeleton_Design_Synthesis_and_Structural_Analysis/2177980
下载链接
链接失效反馈官方服务：
资源简介：
A series
of Cu(I), Ag(I), and Au(I) complexes incorporating a new
family of imidazopyridin-3-ylidene ligands substituted by a diphenylpyrrolidino
group at N(1) and aryl groups at C(5) has been synthesized and their
structures determined by X-ray diffraction analysis. This structural
study has revealed an extremely high steric protection of the metal
center by the bulky heterobicyclic carbenes, while the inversion at
the exocyclic N(sp3) atom provides a remarkable flexibility.
创建时间：
2016-02-13
