Zn(OTf)<sub>2</sub>‑Catalyzed Phosphinylation of Propargylic Alcohols: Access to γ‑Ketophosphine Oxides
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资源简介：
The first facile and efficient Zn(OTf)2-catalyzed direct coupling of unprotected propargylic alcohols with arylphosphine oxides has been developed, affording a general, one-step approach to access structurally diverse γ-ketophosphine oxides via sequential Meyer–Schuster rearrangement/phospha-Michael reaction along with new C(sp3)P and CO bond formations, operational simplicity, and complete atom economy under ligand-free and base-free conditions.
创建时间：
2017-10-24
