Aza-BODIPY Route to Ageladine A
收藏NIAID Data Ecosystem2026-03-13 收录
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https://figshare.com/articles/dataset/Aza-BODIPY_Route_to_Ageladine_A/19131443
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资源简介：
The marine natural
product ageladine A was synthesized by exploiting
novel aza-BODIPY-type boron complexes that allowed the regioselective
dibromination of the pyrrole unit, as confirmed by quantum chemical
calculation (ωB97XD/TApr-cc-pVDZ). The parent tricycle was accessed
by Suzuki–Miyaura cross-coupling employing Buchwald’s
precatalyst. The boron complex of ageladine A exhibited strong fluorescence
that was greater than that of the natural product by a factor of ∼30
and that disappeared in the presence of 2-azido groups.
创建时间：
2022-02-07
